Lu Cheng, Lu Xiyan
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai, 200032, China.
Org Lett. 2002 Dec 26;4(26):4677-9. doi: 10.1021/ol0270733.
[reaction: see text] A highly efficient method for constructing heterocycles was achieved by phosphine-catalyzed tandem umpolung addition and intramolecular conjugate addition. This strategy offers a simple and promising method for constructing synthetically useful heterocycles under neutral conditions with high atom economy.
[反应：见正文] 通过膦催化的串联极性翻转加成和分子内共轭加成实现了一种构建杂环的高效方法。该策略为在中性条件下以高原子经济性构建具有合成用途的杂环提供了一种简单且有前景的方法。
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