Jiang Xia, Jing Xin, Gao Xuesheng, Ou Ziqing
Laboratory of Terrestrial Ecological Process, Institute of Applied Ecology, Chinese Academy of Sciences, Shenyang 110016.
Ying Yong Sheng Tai Xue Bao. 2002 Sep;13(9):1179-86.
The solubility and adsorption/desorption equilibrium of PAHs in soil and their interaction with soil bacterium can be altered by surfactants, which lead to the alternation of PAHs bioavailability. The bioavailability of PAHs can be enhanced by the decrease of interface tension between soil and water, the increasement of PAHs' solubility, and the transportation facilitation of PAHs in the presence of surfactants. It also can be inhibited by the surfactant toxicity to the bacteria or by the competitive ultilization between non-toxicitic surfactants and PAHs by the bacteria. In addition, the effects of surfactants on the PAHs of different existence-forms in soils are different. The bioavailability of PAHs can be affected by the type and concentrion of surfactants, PAHs and soil microorganisms, and also by soil physi-chemical characteristics.
表面活性剂可改变多环芳烃(PAHs)在土壤中的溶解度溶解度和吸附/解吸平衡及其与土壤细菌的相互作用,进而导致PAHs生物有效性的改变。表面活性剂可通过降低土壤与水之间的界面张力、提高PAHs的溶解度以及促进PAHs的迁移来增强PAHs的生物有效性。它也可能因表面活性剂对细菌的毒性或因无毒表面活性剂与PAHs被细菌竞争性利用而受到抑制。此外,表面活性剂对土壤中不同存在形态的PAHs的影响也不同。PAHs的生物有效性会受到表面活性剂的类型和浓度、PAHs和土壤微生物的影响,还会受到土壤理化特性的影响。