Guo Haixia, Liang Chenghao
Dalian University of Technology, School of Chemical Engineering, Dalian 116012.
Sheng Wu Yi Xue Gong Cheng Xue Za Zhi. 2002 Dec;19(4):589-92.
The corrosion rates of TiNi, CoCrNiW and CoCrNiMo were measured in Tyrode's solution with potentiodynamic linear polarization, fore-point weak polarization, Cao Chunan weak polarization, transient linear polarization and atomic absorption spectroscopy. Results indicated that corrosion rates of these three alloys were very low due to their excellent corrosion resistance and the corrosion resistance of CoCrNiMo was the best. Corrosion rates of TiNi, CoCrNiW and CoCrNiMo were 0.691, 0.0595, 0.0490 micron/a and 0.0528, 0.0383, 0.0387 micron/a, respectively. The results measured by the first three methods were about ten times of those by the latter two methods, this was related to the applicability of each method and the alloy surface state. Transient linear polarization technique can determine low corrosion rate conveniently and quickly. Atomic absorption spectroscopy method, determining directly the concentration of ion in solution, and thus provide reference for material biocompatibility. And these two methods are properly used in measuring corrosion rates for biomedical materials.
采用动电位线性极化、前点弱极化、曹楚南弱极化、瞬态线性极化和原子吸收光谱法在泰罗德溶液中测量了TiNi、CoCrNiW和CoCrNiMo的腐蚀速率。结果表明,这三种合金的腐蚀速率很低,因其具有优异的耐腐蚀性,且CoCrNiMo的耐腐蚀性最佳。TiNi、CoCrNiW和CoCrNiMo的腐蚀速率分别为0.691、0.0595、0.0490微米/年和0.0528、0.0383、0.0387微米/年。前三种方法测得的结果约为后两种方法的十倍,这与每种方法的适用性和合金表面状态有关。瞬态线性极化技术能够方便快捷地测定低腐蚀速率。原子吸收光谱法直接测定溶液中离子的浓度,从而为材料的生物相容性提供参考。并且这两种方法适用于测量生物医学材料的腐蚀速率。