Pfingsten W, Soler J M
Waste Management Laboratory, Paul Scherrer Institute, CH-5232 Villigen PSI, Switzerland.
J Contam Hydrol. 2003 Mar;61(1-4):387-403. doi: 10.1016/S0169-7722(02)00120-1.
The investigation of the migration of a high pH plume in a fractured shear zone is foreseen by a long-term experiment at the Grimsel rock laboratory. In order to characterise the initial conditions for the long-term experiment and to evaluate an optimal hydraulic in situ set-up, several dipole experiments with nonreacting tracers have been performed. The dipole experiments differ in geometry, pumping rates and orientation to the background water flow. Several single and double-porosity models have been applied to fit the results of these dipole tracer tests in order to extract values for some transport parameters and discriminate for certain transport processes. A two-dimensional porous medium approach was successfully used to fit tracer breakthrough curves measured for a dipole experiment. A model based on a one-dimensional dual porous medium approach was also successful, although the applied hydraulic dipole, with similar injection and extraction rates, suggests the existence of an extended two-dimensional flow field. For the two-dimensional porous medium approach, tracer breakthrough could only be fitted with a complex flow field geometry within the heterogeneous fractured shear zone. The heterogeneity was generated by heterogeneous porosity and hydraulic permeability distributions. Predictions for further dipole geometries and a sorbing tracer have been calculated by means of both models using the flow and transport parameters deduced from fits for a single dipole experiment. This allows for comparison with the measured breakthrough of sorbing tracers. The foreseen experiment with sorbing (radionuclide) tracers will help decide on the appropriate approach that should be used to describe such dipole experiments in this shear zone. Additionally, the migration and spreading of a solution with high pH has been calculated taking into account mineral dissolution and precipitation in a two-dimensional porous medium approach in order to estimate the amount and character of the mineral reactions induced by the interaction between the high pH solution and the rock.
格里姆瑟尔岩石实验室的一项长期实验预计将对高pH值羽状物在断裂剪切带中的迁移进行研究。为了确定长期实验的初始条件并评估最佳的现场水力设置,已进行了多项使用非反应性示踪剂的偶极实验。这些偶极实验在几何形状、抽水速率以及与背景水流的方向上存在差异。已应用了几种单孔隙度和双孔隙度模型来拟合这些偶极示踪剂测试的结果,以便提取一些传输参数的值并区分某些传输过程。二维多孔介质方法成功地用于拟合为一个偶极实验测量的示踪剂突破曲线。基于一维双孔隙介质方法的模型也取得了成功,尽管所应用的水力偶极具有相似的注入和提取速率,但这表明存在一个扩展的二维流场。对于二维多孔介质方法,示踪剂突破只能通过非均质断裂剪切带内的复杂流场几何形状来拟合。这种非均质性是由孔隙度和水力渗透率的非均质分布产生的。已通过这两种模型利用从单个偶极实验拟合中推导的流动和传输参数,计算了进一步偶极几何形状和吸附性示踪剂的预测结果。这使得能够与测量的吸附性示踪剂突破进行比较。预计进行的吸附性(放射性核素)示踪剂实验将有助于确定在这个剪切带中描述此类偶极实验应采用的合适方法。此外,已在二维多孔介质方法中考虑矿物溶解和沉淀,计算了高pH值溶液的迁移和扩散,以便估计高pH值溶液与岩石相互作用引起的矿物反应的量和特征。