Omary Mohammad A, Kassab Refaie M, Haneline Mason R, Elbjeirami O, Gabbaï François P
Departments of Chemistry, University of North Texas, Denton, Texas 76203, USA.
Inorg Chem. 2003 Apr 7;42(7):2176-8. doi: 10.1021/ic034066h.
The interaction of the trinuclear mercury(II) complex [(o-C(6)F(4)Hg)(3)] (1) and pyrene leads to the formation of the 1:1 adduct 1.pyrene. The crystal structure of this adduct reveals the existence of supramolecular stacks in which molecules of 1 and molecules of pyrene alternate along the infinite chains. Steady-state and time-resolved photoluminescence measurements indicate the occurrence of a heavy atom effect which results in red, green, and blue (RGB) phosphorescent emissions for 1.pyrene, 1.naphthalene, and 1.biphenyl, respectively.
三核汞（II）配合物[(o-C₆F₄Hg)₃]（1）与芘相互作用生成1:1加合物1·芘。该加合物的晶体结构表明存在超分子堆积，其中1的分子和芘的分子沿着无限长链交替排列。稳态和时间分辨光致发光测量表明存在重原子效应，分别导致1·芘、1·萘和1·联苯产生红色、绿色和蓝色（RGB）磷光发射。
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