An unprecedented trans-oriented product from the cleavage of a dipeptide.
作者信息
Saha Manas K, Bernal Ivan
机构信息
Department of Chemistry, University of Houston, Houston, Texas 77204-5641, USA.
出版信息
Chem Commun (Camb). 2003 Mar 7(5):612-3. doi: 10.1039/b212587k.
DOI:10.1039/b212587k
PMID:12669850
Abstract
An unusual trans cleavage reaction was observed when trans-[Co(3,2,3-tet)Cl2]Cl (3,2,3-tet = N,N'-bis(3-aminopropyl)ethylenediamine), was allowed to react with beta-alanyl-L-histidine (a bioactive dipeptide) in an aqueous medium at pH approximately 7.5 and 45 degrees C for 6 h.
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