由果糖一锅两步法实用催化合成2,5-二甲基呋喃。
One-pot, two-step, practical catalytic synthesis of 2,5-diformylfuran from fructose.
作者信息
Halliday Gary A, Young Robert J, Grushin Vladimir V
机构信息
Central Research and Development, E. I. DuPont de Nemours & Co., Inc., Experimental Station, Wilmington, Delaware 19880-0328, USA.
出版信息
Org Lett. 2003 May 29;5(11):2003-5. doi: 10.1021/ol034572a.
PMID:12762707
Abstract
[reaction: see text] A practical, one-pot, two-step catalytic method is described for the synthesis of 2,5-diformylfuran (DFF) from fructose via dehydration to 5-(hydroxymethyl)furfural (HMF), followed by in situ catalytic air-oxidation.
摘要
[反应：见正文] 描述了一种实用的一锅两步催化方法，用于从果糖合成2,5-二甲基呋喃（DFF），先将果糖脱水生成5-（羟甲基）糠醛（HMF），然后进行原位催化空气氧化。
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