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用于甲烷去除的贵金属催化剂。

Noble metal catalysts for methane removal.

作者信息

Janbey Alan, Clark Wayne, Noordally Ehsan, Grimes Sue, Tahir Saad

机构信息

The London College, University College Kensington, Victoria Gardens, W11 3PE, London, UK.

出版信息

Chemosphere. 2003 Aug;52(6):1041-6. doi: 10.1016/S0045-6535(03)00292-3.

Abstract

Using a bench-scale rig, the activities of Pt, Pd and Pt+Pd catalysts supported on gamma-Al(2)O(3) and on TiO(2) (anatase) for the complete oxidation of methane (300 ppmv) in air have been measured as a function of temperature; values of T(10), T(50) and T(90) together with the Arrhenius parameters (activation energy and pre-exponential factor) are reported. Pt is less active than Pd when deposited on the surface of the TiO(2), but more active when deposited on gamma-Al(2)O(3), however when combined, the Pt+Pd mixture is more active than either metal individually. The T(10) for Pt+Pd/gamma-Al(2)O(3) was being as low as 228 degrees C. The significance of the Arrhenius parameters, for metal containing catalysts is that they exhibit compensation with increasing activation energy, while securing a more rapid increase in conversion from 0% to 100% when the temperature is increased.

摘要

使用小型试验装置,已测量了负载在γ - Al₂O₃和TiO₂(锐钛矿型)上的Pt、Pd以及Pt + Pd催化剂对空气中甲烷(300 ppmv)完全氧化的活性随温度的变化情况;报告了T₁₀、T₅₀和T₉₀的值以及阿累尼乌斯参数(活化能和指前因子)。当沉积在TiO₂表面时,Pt的活性低于Pd,但沉积在γ - Al₂O₃上时活性更高,然而,当两者组合时,Pt + Pd混合物的活性比任何一种金属单独存在时都更高。Pt + Pd/γ - Al₂O₃的T₁₀低至228℃。含金属催化剂的阿累尼乌斯参数的意义在于,它们随着活化能的增加而呈现出补偿效应,同时在温度升高时能确保转化率从0%到100%有更快的增加。

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