Churaev N V
The Institute of Physical Chemistry of the Russian Academy of Sciences, Leninsky Prospect 31, 119991, Moscow, Russia.
Adv Colloid Interface Sci. 2003 May 30;103(3):197-218. doi: 10.1016/S0001-8686(02)00074-X.
A short review of various components of surface forces acting in a non-symmetrical system such as wetting films is presented here. Experimental results are compared with modified DLVO theory, which includes, besides dispersion and electrostatic, structural (solvation) forces caused by a change in liquid structure in conditions of confined geometry. The peculiarities of disjoining pressure isotherms and conditions of the film stability of non-polar and polar simple liquids, as well as of aqueous solutions of electrolytes and surfactants, are systematically considered from a historical perspective.
本文简要回顾了作用于非对称体系（如润湿膜）中的表面力的各个组成部分。将实验结果与修正的DLVO理论进行了比较，该理论除了包括色散力和静电力外，还包括在受限几何条件下由液体结构变化引起的结构（溶剂化）力。从历史的角度系统地考虑了非极性和极性简单液体以及电解质和表面活性剂水溶液的分离压力等温线的特性和膜稳定性条件。
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