Kalyuzhnyi Sergey, Sklyar Vladimir, Epov Andrey, Arkhipchenko Irina, Barboulina Irina, Orlova Olga, Kovalev Alexander, Nozhevnikova Alla, Klapwijk Abraham
Institute of Agricultural Microbiology, Podbelsky shosse 3, 189620 St. Petersburg-Pushkin 8, Russia.
Appl Biochem Biotechnol. 2003 Apr-Jun;109(1-3):77-94. doi: 10.1385/abab:109:1-3:77.
This article summarizes the results obtained during the laboratory and pilot development of integrated biologic and physicochemical treatment and reuse of diluted pig manure streams. The application of a straw filter was an effective means to separate the solid and liquid fractions of raw wastewater and resulted in the removal of a significant part of the dry matter, total nitrogen, and phosphorus (65, 27, and 32%, respectively). From the filtrate generated, 60-80% of the total chemical oxygen demand (COD) was removed in an upflow anaerobic sludge bed reactor operating at 15-30 degrees C. Ammonia was efficiently eliminated (>99%) from the anaerobic effluents using Ural laumantite as an ion exchanger. However, the nitrogen-content of the zeolite was too low to consider this method of ammonia removal economically feasible. The phosphate precipitation block, consisting of stripper of CO2 and fluidized-bed crystallizator, was able to decrease the concentration of soluble phosphate in the anaerobic effluents up to 7-15 mg of phosphate/L. The application of aerobic/anoxic biofilter as a sole polishing step was acceptable from an aesthetic point of view (the effluents were transparent and almost colorless and odorless) and elimination of biochemical oxygen demand (the resting COD was hardly biodegradable). However, the effluent nutrient concentrations (especially nitrogen) were far from the current standards for direct discharge of treated wastewater. We discuss the approaches for further improvement of effluent quality. Finally, we provide an outline of a full-scale system that partially implements the laboratory- and pilotscale results obtained.
本文总结了在实验室和中试阶段对稀释猪粪废水进行生物与物理化学综合处理及回用所取得的成果。应用秸秆过滤器是分离原废水固液成分的有效方法,可去除大部分干物质、总氮和磷(分别为65%、27%和32%)。在15 - 30摄氏度运行的上流式厌氧污泥床反应器中,可从产生的滤液中去除60 - 80%的总化学需氧量(COD)。使用乌拉尔片钠铝石作为离子交换剂可有效去除厌氧出水的氨(>99%)。然而,沸石的氮含量过低,以至于该氨去除方法在经济上不可行。由二氧化碳汽提器和流化床结晶器组成的磷酸盐沉淀模块能够将厌氧出水中可溶性磷酸盐的浓度降低至7 - 15毫克磷/升。从美观角度(出水透明且几乎无色无味)以及生化需氧量的去除情况(剩余COD几乎不可生物降解)来看,应用好氧/缺氧生物滤池作为单一的深度处理步骤是可行的。然而,出水营养物浓度(尤其是氮)远未达到当前处理后废水直接排放的标准。我们讨论了进一步提高出水水质的方法。最后,我们概述了一个部分实现实验室和中试阶段成果的全规模系统。