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合成纳米复合材料SiO2/CdS/聚(苯乙烯-共-马来酸酐)和SiO2/CdS/聚(苯乙烯-共-马来酰亚胺)的光学性质

Optical properties of the synthetic nanocomposites SiO2/CdS/poly(styrene-co-maleic anhydride) and SiO2/CdS/poly(styrene-co-maleimide).

作者信息

Esteves Ana Catarina, Monteiro Olinda C, Barros-Timmons Ana M, Boemare Claude, Soares M J, Monteiro Teresa, Trindade Tito

机构信息

Department of Chemistry, University of Aveiro, 3810-193 Aveiro, Portugal.

出版信息

J Nanosci Nanotechnol. 2002 Apr;2(2):177-81. doi: 10.1166/jnn.2002.097.

Abstract

Hybrid materials consisting of SiO2/CdS particles dispersed in poly(styrene-co-maleic anhydride) and poly(styrene-co-maleimide) have been synthesized and characterized. The polymer nanocomposites were synthesised in situ in the presence of previously prepared inorganic fillers (SiO2/CdS). The nanocomposites were synthesized with the use of as-prepared or surface-modified SiO2/CdS fillers. For both types of nanocomposites, the optical properties were evaluated and the observation of size quantization effects in the optical spectra is discussed. In this context, the influence of the inorganic fillers and polymer matrices on the optical properties of the final nanocomposites was investigated.

摘要

由分散在聚(苯乙烯 - 马来酸酐)和聚(苯乙烯 - 马来酰亚胺)中的SiO₂/CdS颗粒组成的杂化材料已被合成并表征。聚合物纳米复合材料是在预先制备的无机填料(SiO₂/CdS)存在下原位合成的。纳米复合材料是使用制备好的或表面改性的SiO₂/CdS填料合成的。对于这两种类型的纳米复合材料,都对其光学性质进行了评估,并讨论了在光谱中尺寸量子化效应的观察结果。在此背景下,研究了无机填料和聚合物基体对最终纳米复合材料光学性质的影响。

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