双（乙腈-κN）[（1RS，4RS，8SR，11SR）-1,4,8,11-四氮杂十四烷-κ（4）N]铜（II）双[四（3,5-双（三氟甲基）苯基）硼酸] 0.31水合物
Bis(acetonitrile-kappaN)[(1RS,4RS,8SR,11SR)-1,4,8,11-tetraazatetradecane-kappa(4)N]copper(II) bis[tetrakis[3,5-bis(trifluoromethyl)phenyl]borate] 0.31-hydrate.
作者信息
Skakle Janet M S, Rangel E Silva Marcus V D, Wardell James L, Wardell Solange M S V
机构信息
Department of Chemistry, University of Aberdeen, Meston Walk, Aberdeen AB24 3UE, Scotland.
出版信息
Acta Crystallogr C. 2003 Oct;59(Pt 10):M413-5. doi: 10.1107/s0108270103016743. Epub 2003 Sep 23.
The title compound, Cu(C(2)H(3)N)(2)(C(10)H(24)N(4))(2).0.31H(2)O, crystallizes as an ionic species with no interactions between the ions. The Cu(II)(cyclam)(MeCN)(2) dication (cyclam is 1,4,8,11-tetraazatetradecane), located on a 2/m symmetry site, forms as a distorted octahedral species with four Cu-N(cyclam) bonds of 2.013 (2) A and two C-N(MeCN) bonds of 2.499 (4) A. The BC(6)H(3)(CF(3))-3,5 anion, located on a twofold axis, is a distorted octahedral species. A small amount of water is present, occupying sites between columns of ions.
标题化合物Cu(C₂H₃N)₂(C₁₀H₂₄N₄)₂·0.31H₂O以离子形式结晶，离子之间无相互作用。位于2/m对称位点上的[Cu(II)(环胺)(乙腈)₂]²⁺双阳离子（环胺为1,4,8,11-四氮杂十四烷）形成一个扭曲的八面体物种，有四条Cu-N(环胺)键，键长为2.013(2) Å，两条C-N(乙腈)键，键长为2.499(4) Å。位于二重轴上的[B[C₆H₃(CF₃)-3,5]₄]⁻阴离子是一个扭曲的八面体物种。存在少量水，占据离子柱之间的位置。
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