Suwa Masayori, Watarai Hitoshi
Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan.
J Chromatogr A. 2003 Sep 26;1013(1-2):3-8. doi: 10.1016/s0021-9673(03)00723-4.
By using an improved apparatus for the observation of magnetophoresis, the magnetophoretic velocity of 2-fluorotoluene droplets including lauric acid was measured in aqueous dysprosium(III) solution. The magnetophoretic velocity of pure 2-fluorotoluene droplets was proportional to the square of the radius. On the other hand, the velocity of the organic droplets including lauric acid in the dysprosium(III) solution showed a deviation from the square radius relationship, more remarkably in smaller droplets than 2 microm in radius. These results indicated that the dysprosium(III)-laurate complex was formed at the liquid-liquid interface. This study is the first report on the detection of the interfacial complex by the magnetophoresis of the microdroplet.
通过使用一种改进的磁泳观测装置,在水溶液中镝(III)溶液中测量了含月桂酸的2-氟甲苯液滴的磁泳速度。纯2-氟甲苯液滴的磁泳速度与半径的平方成正比。另一方面,在镝(III)溶液中含月桂酸的有机液滴的速度偏离了与半径平方的关系,在半径小于2微米的较小液滴中更为明显。这些结果表明,在液-液界面形成了镝(III)-月桂酸络合物。本研究是关于通过微滴磁泳检测界面络合物的首次报道。