通过一类新型刚性供氧连接体实现预先设计的中性二维铂大环的简便自组装。

Facile self-assembly of predesigned neutral 2D pt-macrocycles via a new class of rigid oxygen donor linkers.

作者信息

Das Neeladri, Mukherjee Partha Sarathi, Arif Atta M, Stang Peter J

机构信息

Department of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, UT 84112, USA.

出版信息

J Am Chem Soc. 2003 Nov 19;125(46):13950-1. doi: 10.1021/ja037788g.

DOI:10.1021/ja037788g

PMID:14611218

Abstract

Self-assembly of rigid oxygen donor dicarboxylates such as terephthalate and fumarate with a platinum-containing clip-like acceptor unit afforded neutral macrocyclic rectangles which have been characterized by X-ray single-crystal structure analysis as well as NMR spectroscopy.

摘要

刚性的氧供体二羧酸盐（如对苯二甲酸酯和富马酸酯）与含铂的夹子状受体单元自组装，得到了中性大环矩形，其已通过X射线单晶结构分析以及核磁共振光谱进行了表征。