一种对映体特异性合成P-手性硫代磷酸酯的新方法。非对映体二硫代胸苷基-(3'-5')硫代磷酸酯的制备。
A new approach to stereospecific synthesis of P-chiral phosphorothioates. Preparation of diastereomeric dithymidyl-(3'-5') phosphorothioates.
作者信息
Almer Helena, Szabo Tomas, Stawinski Jacek
机构信息
Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, S-106 91 Stockholm, Sweden.
出版信息
Chem Commun (Camb). 2004 Feb 7(3):290-1. doi: 10.1039/b311912b. Epub 2003 Dec 19.
DOI:10.1039/b311912b
PMID:14740042
Abstract
A new method for stereospecific synthesis of P-chiral phosphorothioates based on intramolecular nucleophile catalysis was developed.
摘要
基于分子内亲核催化，开发了一种立体特异性合成P-手性硫代磷酸酯的新方法。
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