一种获取两种类型一叶萩生物碱的新通用方法：一叶萩碱和（-）-别一叶萩碱的合成。
A new general access to either type of Securinega alkaloids: synthesis of securinine and (-)-allonorsecurinine.
作者信息
Alibés Ramon, Ballbé Marta, Busqué Félix, de March Pedro, Elias Laia, Figueredo Marta, Font Josep
机构信息
Departament de Química, Universitat Autonoma de Barcelona, 08193 Bellaterra, Spain.
出版信息
Org Lett. 2004 May 27;6(11):1813-6. doi: 10.1021/ol049455+.
PMID:15151421
Abstract
The syntheses of securinine and (-)-allonorsecurinine have been achieved starting from easily available alpha-amino acid derivatives and using as key steps a RCM and a Heck reaction for the formation of rings D and C, respectively. [reaction: see text]
摘要
一叶萩碱和（-）-别一叶萩碱的合成已从容易获得的α-氨基酸衍生物开始实现，并分别使用关环复分解反应（RCM）和Heck反应作为关键步骤来形成D环和C环。[反应：见正文]
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