以溴胺 -T 为氮烯源，铁（III）卟啉催化烯烃的氮杂环丙烷化反应。
Iron(III) porphyrin catalyzed aziridination of alkenes with bromamine-T as nitrene source.
作者信息
Vyas Renu, Gao Guang-Yao, Harden Jeremiah D, Zhang X Peter
机构信息
Department of Chemistry, University of Tennessee, Knoxville, Tennessee 37996-1600, USA.
出版信息
Org Lett. 2004 Jun 10;6(12):1907-10. doi: 10.1021/ol049691k.
[reaction: see text] Iron(III) porphyrin complexes Fe(Por)Cl are effective catalysts for aziridination of alkenes using bromamine-T as the nitrene source. The catalytic system can operate under mild conditions with alkenes as limiting reagents. The aziridination reaction is general and suitable for a wide variety of alkenes, including aromatic, aliphatic, cyclic, and acyclic olefins, as well as alpha,beta-unsaturated esters. For 1,2-disubstituted olefins, the reactions proceeded with moderate to low stereospecificity.
[反应：见正文] 铁（III）卟啉配合物Fe（Por）Cl是以溴胺-T作为氮烯源用于烯烃氮杂环丙烷化反应的有效催化剂。该催化体系能在温和条件下以烯烃作为限量试剂运行。氮杂环丙烷化反应具有普遍性，适用于多种烯烃，包括芳香族、脂肪族、环状和非环状烯烃，以及α,β-不饱和酯。对于1,2-二取代烯烃，反应以中等至低的立体专一性进行。
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