利用立体电子效应解释4-取代五元环氧鎓离子的选择性反应。
Using stereoelectronic effects to explain selective reactions of 4-substituted five-membered ring oxocarbenium ions.
作者信息
Smith Deborah M, Woerpel K A
机构信息
Department of Chemistry, University of California-Irvine, Irvine, California 92697-2025, USA.
出版信息
Org Lett. 2004 Jun 10;6(12):2063-6. doi: 10.1021/ol0492647.
PMID:15176819
Abstract
[reaction: see text] The utility of the inside attack model to predict and analyze the stereoselectivities of nucleophilic additions to complex five-membered ring oxocarbenium ions is demonstrated in a systematic study of C-4-substituted acetals.
摘要
[反应：见正文] 内进攻模型在预测和分析亲核加成到复杂五元环氧鎓离子的立体选择性方面的效用，在对C-4-取代缩醛的系统研究中得到了证明。
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