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使用高特异性树脂和液体闪烁计数法测定饮用水中的总α

Gross alpha determination in drinking water using a highly specific resin and LSC.

作者信息

Happel S, Letessier P, Ensinger W, Eikenberg J H, Thakkar A H, Horwitz E P

机构信息

Eichrom Europe, Parc de Lormandière, Bât. C, Rue Maryse Bastié, Campus de Ker Lann, Bruz 35170, France.

出版信息

Appl Radiat Isot. 2004 Aug-Sep;61(2-3):339-44. doi: 10.1016/j.apradiso.2004.03.005.

Abstract

Some results of experiments concerning a new highly specific resin for the extraction of alpha-emitting nuclides from drinking water samples are presented. The product used during these experiments is a new extraction chromatographic resin which consists of a combination of several reagents and extractants supported on inert polymeric substrates, called "Resin" hereafter. It shows strong affinity for Actinides in the tri-, tetra- and hexavalent oxidation state, as well as for radium, even in presence of large amounts of calcium. Gross-alpha activities were determined using alpha-/beta-discrimination liquid scintillation counting (alpha-/beta-LSC) by direct measurement of the dried resin after extraction. Counting conditions were optimised accordingly. A method for the determination of alpha-emitting nuclides in drinking water was developed and tested using intercomparison and spiked drinking water samples.

摘要

介绍了一些关于一种新型高特异性树脂从饮用水样品中提取发射α粒子核素的实验结果。这些实验中使用的产品是一种新型萃取色谱树脂,它由几种试剂和萃取剂组合而成,负载在惰性聚合物基质上,以下简称“树脂”。它对三价、四价和六价氧化态的锕系元素以及镭具有很强的亲和力,即使在存在大量钙的情况下也是如此。通过萃取后对干燥树脂的直接测量,使用α/β甄别液体闪烁计数法(α/β-LSC)测定总α活度。相应地优化了计数条件。开发并使用比对和加标饮用水样品测试了一种测定饮用水中发射α粒子核素的方法。

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