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利用黑曲霉对低品位矿石中的重金属进行生物浸出。

Bioleaching of heavy metals from a low-grade mining ore using Aspergillus niger.

作者信息

Mulligan Catherine N, Kamali Mahtab, Gibbs Bernard F

机构信息

Department of Building Civil and Environmental Engineering, Concordia University, 1455 de Maisonneuve Blvd. W., Montreal H3G 1M8, Canada.

出版信息

J Hazard Mater. 2004 Jul 5;110(1-3):77-84. doi: 10.1016/j.jhazmat.2004.02.040.

Abstract

The main concern of this study is to develop a feasible and economical technique to microbially recover metals from oxide low-grade ores. Owing to the significant quantities of metals that are embodied in low-grade ores and mining residues, these are potential viable sources of metals. In addition, they potentially endanger the environment, as the metals they contain may be released to the environment in hazardous form. Hence, mining industries are seeking an efficient, economic technique to handle these ores. Pyrometallurgical and hydrometallurgical techniques are either very expensive, energy intensive or have a negative impact on the environment. For these reasons, biohydrometallurgical techniques are coming into perspective. In this study, by employing Aspergillus niger, the feasibility of recovery of metals from a mining residue is shown. A. niger exhibits good potential in generating a variety of organic acids effective for metal solubilization. Organic acid effectiveness was enhanced when sulfuric acid was added to the medium. Different agricultural wastes such as potato peels were tested. In addition, different auxiliary processes were evaluated in order to either elevate the efficiency or reduce costs. Finally, maximum solubilization of 68%, 46% and 34% were achieved for copper, zinc and nickel, respectively. Also iron co-dissolution was minimized as only 7% removal occurred.

摘要

本研究的主要关注点是开发一种可行且经济的技术,用于从低品位氧化矿石中微生物回收金属。由于低品位矿石和采矿残渣中蕴含大量金属,它们是潜在的可行金属来源。此外,它们可能危害环境,因为其中所含金属可能以有害形式释放到环境中。因此,采矿业正在寻求一种高效、经济的技术来处理这些矿石。火法冶金和湿法冶金技术要么成本高昂、能源密集,要么对环境有负面影响。出于这些原因,生物湿法冶金技术正受到关注。在本研究中,通过使用黑曲霉,展示了从采矿残渣中回收金属的可行性。黑曲霉在产生多种有效溶解金属的有机酸方面具有良好潜力。向培养基中添加硫酸可提高有机酸的有效性。测试了不同的农业废弃物,如土豆皮。此外,还评估了不同的辅助工艺,以提高效率或降低成本。最终,铜、锌和镍的最大溶解率分别达到了68%、46%和34%。铁的共溶解也降至最低,仅去除了7%。

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