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在[Cu(己二酸)(4,4-联吡啶)].(H₂O)₂的晶体主体中一个结构清晰的uudd环状水四聚体

A well-resolved uudd cyclic water tetramer in the crystal host of [Cu(adipate)(4,4-bipyridine)].(H2O)2.

作者信息

Long La-Sheng, Wu Yan-Rong, Huang Rong-Bin, Zheng Lan-Sun

机构信息

Department of Chemistry and State Key Laboratory of Physical Chemistry of Solid Surface, Xiamen University, Xiamen 361005, China.

出版信息

Inorg Chem. 2004 Jun 28;43(13):3798-800. doi: 10.1021/ic0494354.

Abstract

A well-resolved uudd cyclic water tetramer was reported in the crystal host of [Cu(adipate)(4,4-bipyridine)].(H(2)O)(2), showing the contribution of the water cluster to the stability of the crystal host and the role of cooperative association of the water cluster and the crystal host in the formation of the water cluster.

摘要

在[Cu(己二酸)(4,4-联吡啶)].(H₂O)₂的晶体主体中报道了一种解析良好的uudd环状水四聚体,显示了水簇对晶体主体稳定性的贡献以及水簇与晶体主体协同缔合在水簇形成中的作用。

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