van Zon R, Cohen E G D
The Rockefeller University, 1230 York Avenue, New York, New York 10021, USA.
Phys Rev E Stat Nonlin Soft Matter Phys. 2004 May;69(5 Pt 2):056121. doi: 10.1103/PhysRevE.69.056121. Epub 2004 May 28.
Heat fluctuations over a time tau in a nonequilibrium stationary state and in a transient state are studied for a simple system with deterministic and stochastic components: a Brownian particle dragged through a fluid by a harmonic potential which is moved with constant velocity. Using a Langevin equation, we find the exact Fourier transform of the distribution of these fluctuations for all tau. By a saddle-point method we obtain analytical results for the inverse Fourier transform, which, for not too small tau, agree very well with numerical results from a sampling method as well as from the fast Fourier transform algorithm. Due to the interaction of the deterministic part of the motion of the particle in the mechanical potential with the stochastic part of the motion caused by the fluid, the conventional heat fluctuation theorem is, for infinite and for finite tau, replaced by an extended fluctuation theorem that differs noticeably and measurably from it. In particular, for large fluctuations, the ratio of the probability for absorption of heat (by the particle from the fluid) to the probability to supply heat (by the particle to the fluid) is much larger here than in the conventional fluctuation theorem.
对于一个具有确定性和随机成分的简单系统,即一个由以恒定速度移动的简谐势拖动通过流体的布朗粒子,研究了在非平衡稳态和瞬态下时间τ内的热涨落。使用朗之万方程,我们求出了所有τ下这些涨落分布的精确傅里叶变换。通过鞍点法,我们得到了逆傅里叶变换的解析结果,对于不太小的τ,该结果与采样方法以及快速傅里叶变换算法的数值结果非常吻合。由于粒子在机械势中的确定性运动部分与流体引起的随机运动部分之间的相互作用,对于无限和有限的τ,传统的热涨落定理被一个扩展的涨落定理所取代,该定理与传统定理有明显且可测量的差异。特别是,对于大的涨落,这里粒子从流体吸收热量的概率与粒子向流体供应热量的概率之比比传统涨落定理中的要大得多。