El Zawahry M M, Kamel M M
Dyeing, Printing & Auxiliary Department, National Research Centre, Cairo, Egypt.
Water Res. 2004 Jul;38(13):2967-72. doi: 10.1016/S0043-1354(01)00526-7.
The rate of adsorption of two azo and four anthraquinone anionic dyes on Eichhornia Crassipes (E.C.) has been studied. Raw E.C. and three aminated derivatives of E.C. with different nitrogen percent were used as dye adsorbents. The parameters studied include the amount of substrate, shaking time, chemical structure, concentration of dyestuff and pH of dyeing bath. Simple kinetic adsorption models of dynamics and adsorption parameters for the Langmuir and Freundlich isotherms were determined. A higher nitrogen percent of aminated E.C. showed a higher adsorption capacity than other derivatives. The kinetic adsorption models indicate that the decolourization was complete in a relatively short time (10 min) and the reaction taking place is of the first order. The equilibrium data fit well with the Freundlich model of adsorption for the six dyes. Only dye IV (C.I.A Acid Blue 25) conform both Freundlich and Langmuir adsorption isotherms.
研究了两种偶氮和四种蒽醌阴离子染料在凤眼莲(E.C.)上的吸附速率。使用未处理的凤眼莲和三种不同含氮量的胺化凤眼莲衍生物作为染料吸附剂。研究的参数包括底物量、振荡时间、化学结构、染料浓度和染浴pH值。确定了动力学的简单吸附模型以及朗缪尔和弗伦德里希等温线的吸附参数。胺化凤眼莲含氮量越高,其吸附容量比其他衍生物越高。动力学吸附模型表明,脱色在相对较短的时间(10分钟)内完成,发生的反应为一级反应。六种染料的平衡数据与弗伦德里希吸附模型拟合良好。只有染料IV(C.I.A酸性蓝25)符合弗伦德里希和朗缪尔吸附等温线。