Suppr超能文献

The unphysical pinning of the domain growth during the separation of homopolymer blends near the spinodal.

作者信息

Fiałkowski Marcin, Hołyst Robert

机构信息

Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland.

出版信息

J Chem Phys. 2004 Mar 22;120(12):5802-8. doi: 10.1063/1.1649731.

Abstract

We simulate model B of mesoscopic dynamic with the Flory-Huggins free energy for the homopolymer blend. We concentrate the study on the rescaling of the spatial coordinates in the model. We show that the commonly used rescaling of the spatial coordinates, by the function vanishing at the spinodal, leads to the unphysical freezing of the domains. We study the evolution of the system in two different processes: One is the growth process induced by the temperature quench to the metastable or unstable region of the phase diagram and the second is the quench-jump process in which we first allow the system to separate below the spinodal and next heat it up below or above the spinodal. The proper rescaling avoiding the unphysical pinning of the domain growth at the spinodal is proposed.

摘要

文献AI研究员

20分钟写一篇综述,助力文献阅读效率提升50倍。

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

文档翻译

学术文献翻译模型,支持多种主流文档格式。

立即体验