ten Brinke Gerrit, Ikkala Olli
Materials Science Centre, University of Groningen, Nijenborgh 4, 9747 AG, The Netherlands.
Chem Rec. 2004;4(4):219-30. doi: 10.1002/tcr.20018.
Block copolymer self-assembly and supramolecular chemistry can be combined most naturally to prepare smart polymer nanomaterials. An attractive route is based on comb-shaped supramolecules, obtained by attaching side chains to (co)polymers by physical (non-covalent) interactions. Hydrogen bonding is a key element of our approach. It combines an ease of synthesis with other important approach-specific elements, such as hierarchical self-assembly, strongly enhanced processability, swelling, and cleaving. Functional properties discussed include anisotropic proton conductivity, switching proton conductivity, electronically conducting nanowires, polarized luminance, dielectric stacks (optical reflectivity), functional membranes, and nano objects.
嵌段共聚物自组装与超分子化学能够最自然地结合起来，以制备智能聚合物纳米材料。一条颇具吸引力的途径是基于梳状超分子，它是通过物理（非共价）相互作用将侧链连接到（共）聚合物上而得到的。氢键是我们方法的关键要素。它将合成的简便性与其他重要的特定方法要素相结合，如分级自组装、显著增强的可加工性、溶胀和裂解。所讨论的功能特性包括各向异性质子传导性、开关质子传导性、导电纳米线、偏振发光、介电堆叠（光学反射率）、功能膜和纳米物体。
