通过两个取代吲哚中的C-H...F和C-H...π相互作用进行晶体工程。
Crystal engineering via C-H...F and C-H...pi interactions in two substituted indoles.
作者信息
Choudhury A R, Nagarajan K, Row T N Guru
机构信息
Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore 560 012, Karnataka, India.
出版信息
Acta Crystallogr C. 2004 Sep;60(Pt 9):o644-7. doi: 10.1107/S0108270104016865. Epub 2004 Aug 11.
The crystal structures of 1-(4-fluorophenyl)-2-phenyl-4,5,6,7-tetrahydro-1H-indole, C20H18FN, and 1-(4-fluorophenyl)-6,6-dimethyl-2-phenyl-4,5,6,7-tetrahydro-1H-indole, C22H22FN, have been determined in order to study the role of 'organic fluorine' in crystal engineering. These molecules pack in the crystal structure via different types of molecular motifs utilizing weak C-H...F and C-H...pi interactions.
为了研究“有机氟”在晶体工程中的作用，已测定了1-(4-氟苯基)-2-苯基-4,5,6,7-四氢-1H-吲哚（C20H18FN）和1-(4-氟苯基)-6,6-二甲基-2-苯基-4,5,6,7-四氢-1H-吲哚（C22H22FN）的晶体结构。这些分子通过利用弱C-H...F和C-H...π相互作用的不同类型分子基序堆积在晶体结构中。
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