Antonietti Markus, Kuang Daibin, Smarsly Bernd, Zhou Yong
Max Planck Institute of Colloids and Interfaces, Research Campus Golm, 14424 Potsdam, Germany.
Angew Chem Int Ed Engl. 2004 Sep 27;43(38):4988-92. doi: 10.1002/anie.200460091.
Ionic liquids are a new class of organic solvents with high polarity and a preorganized solvent structure. Very polar reactions can be carried out in these liquid in the absence of or with a controlled amount of water, and crystalline nanoparticles can be synthesized conveniently at ambient temperatures. The pronounced self-organization of the solvent is used in the synthesis of self-assembled, highly organized hybrid nanostructures with unparalleled quality. The extraordinary potential of ionic liquids in materials synthesis is described in this minireview and a physicochemical explanation is given.
离子液体是一类新型的具有高极性和预组织溶剂结构的有机溶剂。在无水或控制水量的情况下,可在这些液体中进行强极性反应,并且能够在环境温度下方便地合成结晶纳米颗粒。溶剂显著的自组织特性被用于合成具有无与伦比质量的自组装、高度有序的混合纳米结构。本综述介绍了离子液体在材料合成方面的非凡潜力,并给出了物理化学解释。