含4,4'-联吡啶的金-铊超分子阵列。溶剂诱导的发光网络。
Gold-thallium supramolecular arrays with 4,4'-bipyridine. Solvent induction of luminescent networks.
作者信息
Fernandez Eduardo J, Laguna Antonio, Lopez-De-Luzuriaga Jose Maria, Olmos M Elena, Perez Javier
机构信息
Departamento de Química, Universidad de la Rioja, Grupo de Síntesis Química de La Rioja, UA-CSIC, Complejo Científico Tecnológico, 26006 Logroño, Spain.
出版信息
Dalton Trans. 2004 Jun 21(12):1801-6. doi: 10.1039/b404703f. Epub 2004 May 19.
The reaction of AuTl(C(6)Cl(5))(2) with bipy at different molar ratios, solvents or crystallisation conditions affords a series of two- and three-dimensional luminescent complexes, AuTl(C(6)Cl(5))(2)(bipy)(0.5), AuTl(C(6)Cl(5))(2)(bipy), [Tl(bipy)][Tl(bipy)(0.5)(THF)]Au(C(6)Cl(5))(2), [Tl(bipy)][Tl(bipy)(0.5)(THF)]Au(C(6)Cl(5))(2)xTHF and [AuTl(C(6)Cl(5))(2)(bipy)]x0.5toluene(bipy = 4,4'-bipyridine; THF = tetrahydrofuran) all of them containing polymeric chains formed via unsupported Au...Tl interactions and bridging bipyridine ligands.
[AuTl(C₆Cl₅)₂]ₙ与联吡啶在不同摩尔比、溶剂或结晶条件下反应，得到一系列二维和三维发光配合物，[AuTl(C₆Cl₅)₂(bipy)₀.₅]ₙ、[AuTl(C₆Cl₅)₂(bipy)]ₙ、[[Tl(bipy)][Tl(bipy)₀.₅(THF)][Au(C₆Cl₅)₂]₂]ₙ、[[Tl(bipy)][Tl(bipy)₀.₅(THF)][Au(C₆Cl₅)₂]₂·THF]ₙ和[[AuTl(C₆Cl₅)₂(bipy)]·0.5甲苯]ₙ（bipy = 4,4'-联吡啶；THF = 四氢呋喃），它们都含有通过无支撑的Au…Tl相互作用和桥联联吡啶配体形成的聚合物链。
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