基于具有脲和硫脲结合位点受体的高效且简单的比色氟离子传感器。
Efficient and simple colorimetric fluoride ion sensor based on receptors having urea and thiourea binding sites.
作者信息
Jose D Amilan, Kumar D Krishna, Ganguly Bishwajit, Das Amitava
机构信息
Central Salt and Marine Chemicals Research Institute, Bhavnagar 364002, Gujarat, India.
出版信息
Org Lett. 2004 Sep 30;6(20):3445-8. doi: 10.1021/ol048829w.
[structure: see text] Novel colorimetric receptors for selective fluoride ion sensing containing anthraquinone as chromogenic signaling subunit and urea (N,N' '-(9,10-dihydro-9,10-dioxo-1,2-anthracenediyl)bis[N'-phenyl])/thiourea (N,N' '-(9,10-dihydro-9,10-dihydro-9,10-dioxo-1,2-antrhacenediyl)bis[N-phenyl]) binding sites have been reported. These receptors have shown no affinity for other halide ions (Cl-, Br-, and I- ions). Well-defined color change in the visible region of the spectrum was observed upon addition of fluoride ion in DMSO/CH3CN solution of the receptors 1 and 2.
[结构：见正文] 已报道了用于选择性氟离子传感的新型比色受体，其含有蒽醌作为发色信号亚基以及脲（N，N''-（9,10-二氢-9,10-二氧代-1,2-蒽二基）双[N'-苯基]）/硫脲（N，N''-（9,10-二氢-9,10-二氢-9,10-二氧代-1,2-蒽二基）双[N-苯基]）结合位点。这些受体对其他卤离子（Cl-、Br-和I-离子）没有亲和力。在受体1和2的二甲基亚砜/乙腈溶液中加入氟离子后，在光谱的可见区域观察到明确的颜色变化。
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