一种用于钯催化芳基卤化物铃木-宫浦交叉偶联反应的活性二茂铁基三芳基膦。
An active ferrocenyl triarylphosphine for palladium-catalyzed Suzuki-Miyaura cross-coupling of aryl halides.
作者信息
Kwong Fuk Yee, Chan Kin Shing, Yeung Chi Hung, Chan Albert S C
机构信息
Open Laboratory of Chirotechnology of the Institute of Molecular Technology for Drug Discovery and Synthesis, Department of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, Hung Hom, Hong Kong.
出版信息
Chem Commun (Camb). 2004 Oct 21(20):2336-7. doi: 10.1039/b407661c. Epub 2004 Sep 21.
DOI:10.1039/b407661c
PMID:15490008
Abstract
Pd-catalyzed Suzuki-Miyaura reaction of aryl chlorides was accomplished through the use of an active ferrocene-based triarylphosphine ligand. This air- and moisture-stable ligand was found to be effective for the cross-coupling of aryl halides at room temperature to 115 degrees C.
摘要
通过使用一种基于二茂铁的活性三芳基膦配体实现了芳基氯的钯催化铃木-宫浦反应。发现这种对空气和湿气稳定的配体在室温至115摄氏度下对芳基卤化物的交叉偶联有效。
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