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电晕自由基簇射系统对甲苯的分解特性

Decomposition characteristics of toluene by a corona radical shower system.

作者信息

Wu Zu-liang, Gao Xiang, Luo Zhong-yang, Ni Ming-jiang, Cen Ke-fa

机构信息

Clean Energy and Environment Engineering Key Lab of Ministry of Education, Zhejiang University, Hangzhou 310027, China.

出版信息

J Environ Sci (China). 2004;16(4):543-7.

Abstract

Non-thermal plasma technologies offer an innovative approach to decomposing various volatile organic compounds(VOCs). The decomposition of toluene from simulated flue gas was investigated using a pipe electrode with nozzles for the generation of free radicals. Corona characteristics and decomposition of toluene were investigated experimentally. In addition, the decomposition mechanism of toluene was explored in view of reaction rate. The experimental results showed that the humidity of additional gas has an important effect on corona characteristics and modes and stable streamer corona can be generated through optimizing flow rate and humidity of additional gas. Applied voltage, concentration of toluene, humidity of toluene and resident time are some important factors affecting decomposition efficiency. Under optimizing conditions, the decomposition efficiency of toluene can reach 80%. These results can give a conclusion that the corona radical shower technology is feasible and effective on the removal of toluene in the flue gas.

摘要

非热等离子体技术为分解各种挥发性有机化合物(VOCs)提供了一种创新方法。使用带有喷嘴的管式电极来研究从模拟烟气中分解甲苯,该电极用于产生自由基。通过实验研究了电晕特性和甲苯的分解情况。此外,从反应速率的角度探讨了甲苯的分解机理。实验结果表明,附加气体的湿度对电晕特性和模式有重要影响,通过优化附加气体的流速和湿度可以产生稳定的流光电晕。施加电压、甲苯浓度、甲苯湿度和停留时间是影响分解效率的一些重要因素。在优化条件下,甲苯的分解效率可达80%。这些结果可以得出结论,电晕自由基簇射技术在去除烟气中的甲苯方面是可行且有效的。

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