Zhao Yi, Fu Yan-chun, Shuang-chen Ma, Jian-jun Huang
School of Environmental Science & Engineering, North China Electric Power University, Baoding 071003, China.
J Environ Sci (China). 2004;16(4):674-7.
The highly active absorbent with oxidization based on fly ash, lime and additive was prepared. Experiments of simultaneous desulfurization and denitrification were carried out using fixture bed and duct injection. The influencial factors for the absorptive capacity of the absorbent were studied. The absorptive capacities of 120.7 mg for SO2 and 43.7 mg for NOx were achieved at a Ca/(S + N) molar ratio 1.2, respectively, corresponding removal efficiencies of 87% and 76%, while spent absorbent appeared in the form of dry powder. The optimal temperature and humidity of flue gas treated with this process were shown to be approximately 50 degrees C, and 5% respectively. The mechanism of removal for SO2 and NOx was investigated. In comparison with traditional dry FGD, this process appears to have lower cost, less complicated configuration and simpler disposal of used absorbent. The valuable references can be provided for industrial application by this process. The foreground of application will be vast in China and in the world.
制备了以粉煤灰、石灰和添加剂为基础的高活性氧化型吸收剂。采用固定床和管道喷射进行了同时脱硫脱硝实验。研究了影响吸收剂吸收能力的因素。在钙/(硫+氮)摩尔比为1.2时,吸收剂对SO2的吸收量为120.7mg,对NOx的吸收量为43.7mg,相应的去除效率分别为87%和76%,而废吸收剂呈干粉形式。该工艺处理烟气的最佳温度和湿度分别约为50℃和5%。研究了SO2和NOx的去除机理。与传统的干式烟气脱硫相比,该工艺成本更低,结构更简单,废吸收剂处理更简便。该工艺可为工业应用提供有价值的参考。在中国乃至世界,其应用前景广阔。