以过氧化氢为终端氧化剂、碳酸氢盐为助催化剂、氧代二过氧钼（VI）配合物为催化剂的烯烃高效环氧化方法。
Highly efficient epoxidation method of olefins with hydrogen peroxide as terminal oxidant, bicarbonate as a co-catalyst and oxodiperoxo molybdenum(VI) complex as catalyst.
作者信息
Gharah Narottam, Chakraborty Santu, Mukherjee Alok K, Bhattacharyya Ramgopal
机构信息
Department of Chemistry, Jadavpur University, Kolkata, India.
出版信息
Chem Commun (Camb). 2004 Nov 21(22):2630-2. doi: 10.1039/b408946d. Epub 2004 Sep 28.
DOI:10.1039/b408946d
PMID:15543314
Abstract
A combination of the newly synthesized and structurally characterized compound, [MoO(O2)2(saloxH)](saloxH2= salicylaldoxime) as catalyst, H2O2 as terminal oxidant and NaHCO3 as co-catalyst when stirred in CH3CN (10 cm3) at room temperature (rt) shows a very pronounced efficiency epoxidation of olefinic compounds, the method being green and economical.
摘要
新合成并经结构表征的化合物[MoO(O₂)₂(saloxH)]（saloxH₂ = 水杨醛肟）作为催化剂、H₂O₂作为终端氧化剂以及NaHCO₃作为助催化剂，在室温下于乙腈（10 cm³）中搅拌时，对烯烃化合物表现出非常显著的环氧化效率，该方法绿色且经济。
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