一种用于检测铜（II）的有效荧光化学传感器。

An effective fluorescent chemosensor for the detection of copper(II).

作者信息

Zhou Li-Li, Sun Hao, Zhang Xiao-Hong, Wu Shi-Kang

机构信息

Nano-organic Photoelectronic Laboratory, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100101, China.

出版信息

Spectrochim Acta A Mol Biomol Spectrosc. 2005 Jan 1;61(1-2):61-5. doi: 10.1016/j.saa.2004.03.014.

DOI:10.1016/j.saa.2004.03.014

PMID:15556422

Abstract

The fluorescent compound N-substituted 2,6-bis(benzimidazol-2-yl)pyidine (1) has been synthesized. The fluorescent characteristics of the compound 1 and 2,6-bis(benzimidazol-2-yl)pyidine (2) and the complexes formed between the two compounds and different metal ions have also been investigated. The results show that the compound 1 possesses a specific ability to form complex with Cu(2+) ion, but the compound 2 have not such a property. It is proposed that the specific recognition ability of compound 1 to Cu(2+) may be attributed to the cyclic configuration of this compound in polar solvent.

摘要

荧光化合物N-取代的2,6-双（苯并咪唑-2-基）吡啶（1）已被合成。还研究了化合物1和2,6-双（苯并咪唑-2-基）吡啶（2）的荧光特性以及这两种化合物与不同金属离子形成的配合物。结果表明，化合物1具有与Cu(2+)离子形成配合物的特殊能力，但化合物2没有这种性质。有人提出，化合物1对Cu(2+)的特异性识别能力可能归因于该化合物在极性溶剂中的环状结构。