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纳米二氧化硅熔合晶须复合材料的磨损与力学性能

Wear and mechanical properties of nano-silica-fused whisker composites.

作者信息

Xu H H K, Quinn J B, Giuseppetti A A

机构信息

Paffenbarger Research Center, American Dental Association Foundation, National Institute of Standards and Technology, Building 224, Room A-153, Stop 8546, Gaithersburg, MD 20899-8546, USA.

出版信息

J Dent Res. 2004 Dec;83(12):930-5. doi: 10.1177/154405910408301208.

Abstract

Resin composites must be improved if they are to overcome the high failure rates in large stress-bearing posterior restorations. This study aimed to improve wear resistance via nano-silica-fused whiskers. It was hypothesized that nano-silica-fused whiskers would significantly improve composite mechanical properties and wear resistance. Nano-silicas were fused onto whiskers and incorporated into a resin at mass fractions of 0%-74%. Fracture toughness (mean +/- SD; n = 6) was 2.92 +/- 0.14 MPa.m(1/2) for whisker composite with 74% fillers, higher than 1.13 +/- 0.19 MPa.m(1/2) for a prosthetic control, and 0.95 +/- 0.11 MPa.m(1/2) for an inlay/onlay control (Tukey's at 0.95). A whisker composite with 74% fillers had a wear depth of 77.7 +/- 6.9 mum, less than 118.0 +/- 23.8 microm of an inlay/onlay control, and 172.5 +/- 15.4 microm of a prosthetic control (p < 0.05). Linear correlations were established between wear and hardness, modulus, strength, and toughness, with R = 0.95-0.97. Novel nano-silica-fused whisker composites possessed high toughness and wear resistance with smooth worn surfaces, and may be useful in large stress-bearing restorations.

摘要

如果树脂复合材料要克服大型承力后牙修复体的高失败率,就必须加以改进。本研究旨在通过纳米二氧化硅熔合晶须提高耐磨性。研究假设是纳米二氧化硅熔合晶须将显著改善复合材料的机械性能和耐磨性。将纳米二氧化硅熔合到晶须上,并以0%-74%的质量分数掺入树脂中。含74%填料的晶须复合材料的断裂韧性(平均值±标准差;n = 6)为2.92±0.14MPa·m(1/2),高于修复体对照的1.13±0.19MPa·m(1/2)和嵌体/高嵌体对照的0.95±0.11MPa·m(1/2)(Tukey检验,置信度为0.95)。含74%填料的晶须复合材料的磨损深度为77.7±6.9μm,小于嵌体/高嵌体对照的118.0±23.8μm和修复体对照的172.5±15.4μm(p < 0.05)。在磨损与硬度、模量、强度和韧性之间建立了线性相关性,R = 0.95 - 0.97。新型纳米二氧化硅熔合晶须复合材料具有高韧性和耐磨性,磨损表面光滑,可能适用于大型承力修复体。

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