Burford Neil, Spinney Heather A, Ferguson Michael J, McDonald Robert
Department of Chemistry, Dalhousie University, Halifax, Nova Scotia B3H 4J3, Canada.
Chem Commun (Camb). 2004 Dec 7(23):2696-7. doi: 10.1039/b412267d. Epub 2004 Oct 11.
[MesNP(DMAP)2][OTf] represents the first ligand-rich coordination complex of a phosphorus(III) Lewis acceptor, and a three coordinate hypervalent electron-rich (lone pair bearing) center; further diversification is demonstrated by, [(MesNP)2(4,4'-BIPY)][OTf]2, representing an acceptor-rich dication.
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