Stanetty Peter, Schnürch Michael, Mereiter Kurt, Mihovilovic Marko D
Vienna University of Technology, Institute of Applied Synthetic Chemistry and Institute for Chemical Technology and Analytics, Getreidemarkt 9/163, A-1060 Vienna, Austria.
J Org Chem. 2005 Jan 21;70(2):567-74. doi: 10.1021/jo0484326.
The halogen dance (HD) reaction on various 2-thiazolamine systems was investigated providing an easy access to a series of 5-substituted 4-bromo-2-thiazolamine derivatives. We could show that HD is a very favored process for the investigated systems and that prevention of HD is only possible when optimized reaction conditions and selected electrophiles are applied.
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