Wang Y Y, Peng Y Z, Peng C Y, Wang S Y, Zeng W
School of Municipal and Environmental Engineering, Harbin Institute of Technology, Harbin, People's Republic of China 150091.
Water Sci Technol. 2004;50(10):153-61.
The effect of added carbon source and nitrate concentration on the denitrifying phosphorus removal by denitrifying phosphorus removal bacteria sludge was systematically studied using batch experiments, at the same time the variation of ORP was investigated. Results showed that the denitrifying and phosphorus uptake rate in the anoxic phase increased with the high initial anaerobic carbon source addition. However, once the initial COD concentration reached a certain level, which was in excess of the PHB saturation of Poly-p bacteria, residual COD carried over to the anoxic phase inhibited the subsequent denitrifying phosphorus uptake. This was equal to supplementing the external carbon source to the anoxic phase, furthermore the higher the external carbon source concentration the more powerful the inhibition caused. High nitrate concentration in the anoxic phase increased the initial denitrifying phosphorus rate. Oncethe nitrate was exhausted, phosphate uptake changed to phosphate release. Moreover, the time of this turning point occurred later with the higher nitrate addition. On the other hand, through on-line monitoring the variation of the ORP with different initial COD concentration, it was found that ORP could be used as a control parameter for phosphorus release, but it is impossible to utilize ORP for controlling the dinitrification and anoxic phosphorus uptake operations.
采用批次试验系统研究了外加碳源和硝酸盐浓度对反硝化聚磷菌污泥反硝化除磷的影响,同时考察了氧化还原电位(ORP)的变化。结果表明,随着初始厌氧碳源投加量的增加,缺氧阶段的反硝化和吸磷速率提高。然而,当初始COD浓度达到一定水平,即超过聚磷菌的聚-β-羟基丁酸(PHB)饱和度时,进入缺氧阶段的残余COD会抑制后续的反硝化吸磷。这相当于向缺氧阶段补充了外部碳源,而且外部碳源浓度越高,造成的抑制作用越强。缺氧阶段较高的硝酸盐浓度提高了初始反硝化除磷速率。一旦硝酸盐耗尽,磷的吸收就转变为磷的释放。此外,硝酸盐投加量越高,这一转折点出现的时间越晚。另一方面,通过在线监测不同初始COD浓度下ORP的变化发现,ORP可作为磷释放的控制参数,但无法利用ORP来控制反硝化和缺氧吸磷操作。