Achard M-F, Kleman M, Nastishin Yu A, Nguyen H-T
Centre de Recherche Paul Pascal, CNRS, Université Bordeaux 1, Avenue Schweitzer, 33600, Pessac, France.
Eur Phys J E Soft Matter. 2005 Jan;16(1):37-47. doi: 10.1140/epje/e2005-00005-2. Epub 2005 Jan 31.
Deformations that conserve the parallelism and the distances--between layers, in smectic phases; between columns, in columnar phases--are commonplace in liquid crystals. The resulting isometric deformed textures display specific geometric features. The corresponding order parameter singularities extend over rather large, macroscopic, distances, e.g., cofocal conics in smectics. This well-known picture is modified when, superimposed to the 1D or 2D periodicities, the structure is helical. However isometry can be preserved. This paper discusses the case of a medium whose structure is made of 1D modulated layers (a lamello-columnar phase), assuming that the modulations rotate helically from one layer to the next. The price to pay is that any isometric texture is necessarily frustrated; it consists of layers folded into a set of parallel helicoids, in the manner of a screw dislocation (of macroscopic Burgers vector), the modulations being along the helices, i.e. double-twisted. The singularity set is made of two helical disclination lines. We complete this geometric analysis by a crude calculation of the energy of a helical ribbon. It is suggested that the helical ribbons observed in the B7 phase of banana-like molecules are such isometric textures. As a side result, let us mention that the description of double-twist, traditionally made in terms of a partition of the director field into nested cylinders, could more than often be profitably tested against a partition into nested helicoids.
在近晶相中,保持层间平行性和距离的形变;在柱状相中,保持柱间平行性和距离的形变,在液晶中很常见。由此产生的等距形变织构具有特定的几何特征。相应的序参量奇点在相当大的宏观距离上延伸,例如近晶相中的共焦二次曲线。当结构叠加一维或二维周期性且呈螺旋状时,这一众所周知的情况会有所改变。然而,等距性仍可保持。本文讨论一种介质的情况,其结构由一维调制层(层柱状相)构成,假设调制从一层到下一层呈螺旋状旋转。代价是任何等距织构必然受到阻碍;它由折叠成一组平行螺旋面的层组成,类似于(具有宏观伯格斯矢量的)螺旋位错,调制沿螺旋方向,即双螺旋方向。奇点集由两条螺旋位错线组成。我们通过对螺旋带能量的粗略计算来完善这一几何分析。有人认为,在香蕉状分子的B7相中观察到的螺旋带就是这样的等距织构。顺便提一下,传统上用将指向矢场划分为嵌套圆柱来描述双螺旋,很多时候用划分为嵌套螺旋面来检验可能会更有成效。