一种由质子化异烟酸根模板化的新型层状磷酸锌，[Zn2(C6H5NO2)2(HPO4)2] 。
A new layered zinc phosphate templated by protonated isonicotinate, [Zn2(C6H5NO2)2(HPO4)2].
作者信息
Guo Guang Sheng, Wei Yong Ge, Li Jing, Wang Ying, Guo Hong You
机构信息
Department of Chemistry and Chemical Biology, Rutgers University, 610 Taylor Road, Piscataway, New Jersey 08854, USA.
出版信息
Acta Crystallogr C. 2005 Feb;61(Pt 2):m87-9. doi: 10.1107/S0108270104031671. Epub 2005 Jan 15.
An organic-inorganic hybrid compound, poly[bis[(pyridine-4-carboxylato)zinc(II)]-di-mu3-phosphato], [Zn2(C6H5NO2)2(HPO4)2], has been hydrothermally synthesized and structurally characterized. The crystal structure consists of two types of two-dimensional layers of zinc hydrogenphosphate templated by protonated isonicotinate (ina) (or 4-pyridinecarboxylic acid), which contain two crystallographically independent centrosymmetric [Zn2(ina)2(HPO4)2] dimers as basic building units. The layers are interconnected via hydrogen-bonding and heterocyclic ring interactions.
一种有机-无机杂化化合物，聚[双[(吡啶-4-羧酸根)锌(II)]-二-μ3-磷酸根]，[Zn2(C6H5NO2)2(HPO4)2]，已通过水热法合成并进行了结构表征。晶体结构由两种二维层状的磷酸氢锌组成，以质子化的异烟酸（ina）（或4-吡啶羧酸）为模板，其中包含两个晶体学独立的中心对称[Zn2(ina)2(HPO4)2]二聚体作为基本构建单元。这些层通过氢键和杂环相互作用相互连接。
Zotero 插件