Martínez Montero Cristina, Rodríguez Dodero M del Carmen, Guillén Sánchez Dominico Antonio, García Barroso Carmelo
Departamento de Química Analítica, Facultad de Ciencias, Universidad de Cádiz C/República Saharaui s/n, 11510 Puerto Real, Cádiz, Spain.
J Agric Food Chem. 2005 Feb 23;53(4):1058-64. doi: 10.1021/jf0403078.
Brandy de Jerez is aged in American oak casks according to the traditional dynamic system (Soleras y Criaderas) and sometimes additionally by the static system (Anadas). The experimental arrangement used here for the analytical monitoring of brandy aging consisted of 15 casks, 12 of which were set up for aging by the dynamic system, which is well established in the denomination of origin area, whereas the other 3 contained the same brandy but aged according to the static system. This paper studies the kinetics of sugar extraction from oak wood to distillate, as well as the possible correlations between the sugar contents in brandy and its age or the commercial type it belongs to (Solera, Solera Reserva, or Solera Gran Reserva). High-performance anion-exchange chromatography with pulsed amperometric detection was used as the analytical tool to measure the concentrations of glucose, fructose, arabinose, galactose, and xylose, the presence of which in brandy has previously been described.
赫雷斯白兰地采用传统的动态陈酿系统(索莱拉和克里亚德拉斯)在美国橡木桶中陈酿,有时还会采用静态陈酿系统(安达斯)。此处用于分析监测白兰地陈酿过程的实验装置由15个木桶组成,其中12个按照动态系统进行陈酿,该系统在原产地命名区域已得到广泛应用,而另外3个装有相同的白兰地,但按照静态系统进行陈酿。本文研究了橡木中糖分提取到馏出物中的动力学,以及白兰地中糖分含量与其陈酿年份或所属商业类型(索莱拉、索莱拉珍藏或索莱拉特级珍藏)之间可能存在的相关性。采用配有脉冲安培检测的高效阴离子交换色谱法作为分析工具,来测定葡萄糖、果糖、阿拉伯糖、半乳糖和木糖的浓度,此前已有文献描述这些糖类在白兰地中的存在情况。