蝶酸A的对映选择性全合成。

Enantioselective total synthesis of pteridic acid A.

作者信息

Nakahata Takashi, Kuwahara Shigefumi

机构信息

Laboratory of Applied Bioorganic Chemistry, Graduate School of Agricultural Science, Tohoku University, Tsutsumidori-Amamiyamachi, Aoba-ku, Sendai, 981-8555, Japan.

出版信息

Chem Commun (Camb). 2005 Feb 28(8):1028-30. doi: 10.1039/b416309e. Epub 2005 Jan 5.

DOI:10.1039/b416309e

PMID:15719105

Abstract

Pteridic acid A, a potent plant growth promoter with auxin-like activity, was synthesized enantioselectively by using the Evans asymmetric aldol reaction as the key C-C bond forming step.

摘要

蕨酸A是一种具有生长素样活性的强效植物生长促进剂，通过使用埃文斯不对称羟醛反应作为关键的碳-碳键形成步骤，对映选择性地合成了该物质。