通过动态二硫键化学将C60纳入可调卟啉二聚体中。
Inclusion of C60 into an adjustable porphyrin dimer generated by dynamic disulfide chemistry.
作者信息
Kieran Amy L, Pascu Sofia I, Jarrosson Thibaut, Sanders Jeremy K M
机构信息
Department of Chemistry, University of Cambridge, Lensfield Rd, Cambridge, UK CB2 1EW.
出版信息
Chem Commun (Camb). 2005 Mar 14(10):1276-8. doi: 10.1039/b417951j. Epub 2005 Jan 20.
DOI:10.1039/b417951j
PMID:15742050
Abstract
A new, highly flexible porphyrin dimer was isolated in preparative scale from a dynamic disulfide library; this receptor adjusts to fit guests with a wide range of steric requirements and, whilst C60 proved to be an unsuitable template for this library, a new C60-porphyrin complex was isolated and characterised.
摘要
一种新型的、高度灵活的卟啉二聚体以制备规模从动态二硫键库中分离出来；这种受体能够进行调整以适应具有广泛空间需求的客体，虽然事实证明C60对于该库来说是不合适的模板，但一种新的C60 - 卟啉复合物被分离并表征。
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