通过对硝基甲苯的乙醇辅助羰基化光催化形成氨基甲酸酯。
Photocatalytic formation of a carbamate through ethanol-assisted carbonylation of p-nitrotoluene.
作者信息
Maldotti Andrea, Amadelli Rossano, Samiolo Luca, Molinari Alessandra, Penoni Andrea, Tollari Stefano, Cenini Sergio
机构信息
Dipartimento di Chimica, Sezione ISOF--CNR, Università di Ferrara, Via L. Borsari 46, 44100, Ferrara, Italy.
出版信息
Chem Commun (Camb). 2005 Apr 7(13):1749-51. doi: 10.1039/b418571d. Epub 2005 Feb 7.
DOI:10.1039/b418571d
PMID:15791320
Abstract
The nitroarene p-nitrotoluene is converted with a selectivity higher than 85% to the corresponding carbamate at room temperature and atmospheric pressure, using photoexcited particles of TiO2 as catalyst and EtOH as carbonylating species.
摘要
在室温及大气压下，以二氧化钛光激发粒子为催化剂、乙醇为羰基化试剂，硝基芳烃对硝基甲苯能以高于85%的选择性转化为相应的氨基甲酸酯。
Zotero 插件