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2-氨基-5-甲基吡啶鎓(2-氨基-5-甲基吡啶)三氯锌酸盐(II)

2-Amino-5-methylpyridinium (2-amino-5-methylpyridine)trichlorozincate(II).

作者信息

Jin Zhi-Min, Tu Bin, He Lin, Hu Mao-Lin, Zou Jian-Wei

机构信息

College of Pharmaceutical Sciences, Zhejiang University of Technology, Hangzhou 310014, People's Republic of China.

出版信息

Acta Crystallogr C. 2005 Apr;61(Pt 4):m197-9. doi: 10.1107/S0108270105006694. Epub 2005 Mar 18.

Abstract

The title compound, (C6H9N2)[ZnCl3(C6H8N2)], consists of one 2-amino-5-methylpyridinium cation and one (2-amino-5-methylpyridine)trichlorozincate(II) anion, which are held together by N-H...Cl hydrogen bonds and pi-pi interactions. The cation and the pyridine ligand show similar geometric features, except for the N-C bond lengths. Molecules of the title compound are connected by N-H...Cl hydrogen bonds to form chiral chains; these chains are associated further by C-H...Cl hydrogen bonds to form layers, which are in turn linked by pi-pi interactions.

摘要

标题化合物(C6H9N2)[ZnCl3(C6H8N2)]由一个2-氨基-5-甲基吡啶鎓阳离子和一个(2-氨基-5-甲基吡啶)三氯锌酸(II)阴离子组成,它们通过N-H...Cl氢键和π-π相互作用结合在一起。除了N-C键长度外,阳离子和吡啶配体表现出相似的几何特征。标题化合物的分子通过N-H...Cl氢键连接形成手性链;这些链通过C-H...Cl氢键进一步缔合形成层,这些层又通过π-π相互作用相连。

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