Xu F J, Cai Q J, Kang E T, Neoh K G
Langmuir. 2005 Apr 12;21(8):3221-5. doi: 10.1021/la0473714.
The halogen-terminated Si(111) (Si-X, X = Cl, Br) surfaces contain effective initiators for surface-initiated atom transfer radical polymerization. Well-defined polymer-Si hybrids, consisting of covalently tethered (Si-C bonded) functional polymer brushes, can be prepared directly from the Si-X surfaces.
卤原子封端的硅(111)(Si-X,X = Cl,Br)表面含有用于表面引发原子转移自由基聚合的有效引发剂。由共价连接(Si-C键合)的功能性聚合物刷组成的结构明确的聚合物-硅杂化材料可以直接从Si-X表面制备。