Du Bao-An, Shen Shi-Gang, Li Zhi-Ting, Xu Jian-Zhong, Ma Li-Qian, Sun Han-Wen
Analytic Science and Technology Laboratory of Hebei Province, Medicine Department of Chemistry and Environment Science Institute, Hebei University, Baoding 071002, China.
Guang Pu Xue Yu Guang Pu Fen Xi. 2005 Jan;25(1):113-5.
By ICP-AES, the authors established the method to quantitatively determine the trace elements Co and Bi in gelatin. The authors processed the unknown sample with wet digesting method. Trace elements in gelatin could be quantitatively determined at the same time. To correct the spectral interference of Fe to Co at specific wavelength, the Interelement Correction(IEC) model was established. The results of the experiment showed that the IEC model could effectively erase the spectral interference of Fe to Co. The result of the spectral correction was greatly superior to the result where the spectral interference weren't corrected by the IEC model. The method was accurate, quick with high performance and wide linear range. The linear correlation coefficient of the tested elements was over 0.999 90. The relative standard deviation (RSD%) was less than 2.00%. The recovery rates were in the range of 98%-107%.
作者通过电感耦合等离子体发射光谱法(ICP - AES)建立了定量测定明胶中微量元素钴(Co)和铋(Bi)的方法。作者采用湿法消解对未知样品进行处理,可同时定量测定明胶中的微量元素。为校正特定波长下铁对钴的光谱干扰,建立了元素间校正(IEC)模型。实验结果表明,IEC模型能有效消除铁对钴的光谱干扰,光谱校正结果明显优于未采用IEC模型校正光谱干扰的结果。该方法准确、快速,具有高性能和宽线性范围。被测元素的线性相关系数大于0.99990,相对标准偏差(RSD%)小于2.00%,回收率在98% - 107%范围内。