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[中国煤中氟的含量与分布]

[Content and distribution of fluorine in Chinese coals].

作者信息

Wu Dai-she, Zheng Bao-shan, Tang Xiu-yi, Wang Yan, Liu Xiao-jing, Hu Jun, Finkelman R B

机构信息

State Key Lab of Environmental Geochemistry, Institute of Geochemistry, CAS, Guiyang 550002, China.

出版信息

Huan Jing Ke Xue. 2005 Jan;26(1):7-11.

Abstract

Nationwide sampling program is designed according to the resources distribution and coal-forming periods as well as coal rank and yield of coal in China, and 305 coal samples were collected from 26 provinces, municipalities and autonomous regions. Fluorine in coal is determined by pyrohydrolysis / fluoride-ion selective electrode method. Fluorine in coals is mainly of an inorganic nature. Coal rank has no effect on fluorine content. The influence of a factor, such as geological age, on fluorine contents might be concealed by other factors, more research should be done to discern it. The distribution of fluorine in each province, municipality and autonomous region's coals is studied, and the fluorine source in coal-burning endemic fluorosis areas should be estimated over again. The contents of fluorine in Chinese coals show logarithm normal distribution, and 90% of values ranged from 47mg/kg to 347mg/kg, the average fluorine content in Chinese coals was designated as the geometric mean, 136mg/kg. Fluorine in Chinese coals is within the world coal's range.

摘要

全国采样计划是根据中国的资源分布、成煤期以及煤的煤级和产量来设计的,从26个省、直辖市和自治区采集了305个煤样。煤中的氟采用高温水解/氟离子选择性电极法测定。煤中的氟主要为无机性质。煤级对氟含量没有影响。地质年代等因素对氟含量的影响可能被其他因素掩盖,需要做更多研究来识别。研究了各省市自治区煤中氟的分布情况,应重新评估燃煤型地方性氟中毒病区煤中的氟源。中国煤中氟含量呈对数正态分布,90%的值在47mg/kg至347mg/kg之间,中国煤的平均氟含量指定为几何平均值,即136mg/kg。中国煤中的氟含量在世界煤的范围内。

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