Bray David J, Liao Li-Ling, Antonioli Bianca, Gloe Karsten, Lindoy Leonard F, McMurtrie John C, Wei Gang, Zhang Xiao-Yi
Centre for Heavy Metals Research, School of Chemistry, University of Sydney, NSW 2006, Australia.
Dalton Trans. 2005 Jun 21(12):2082-3. doi: 10.1039/b505365j. Epub 2005 May 13.
A trinuclear metallo-capsule has been assembled from a new tripodal pyridyl ligand and three silver(I) ions; the X-ray structure shows the presence of a Ag-Ag interaction in the solid state giving rise to a non-symmetric capsule arrangement while NMR evidence indicates that the structure in solution is symmetrical.
一种三核金属胶囊由一种新型三脚架吡啶配体和三个银(I)离子组装而成;X射线结构表明固态中存在银-银相互作用,产生不对称的胶囊排列,而核磁共振证据表明溶液中的结构是对称的。