Park C H, Chung C W, Lee Y J, Han G B
Department of Environmental Engineering, University of Seoul, Seoul, 130-743, Korea.
Environ Technol. 2005 Jun;26(6):591-600. doi: 10.1080/09593330.2001.9619499.
The utilization of mecellulose wasted liquor (MWL) as an external carbon source was investigated to find an alternative for methanol in the two-stage denitrification pilot process. The pilot plant was supplied with the raw water from the J-Municipal Sewage Treatment Plant (J-MSTP) in Korea. The raw water of J-Municipal Sewage Treatment Plant contains low and high concentration of biodegradable organics and nitrogen source, respectively, due to the inflow of industrial wastewater and landfill leachate. Methanol was fed to provide external carbon source for high concentration of nitrogen source removal by denitrification in this J-Municipal Sewage Treatment Plant, and thus this study was performed to test effects to the effluent quality and efficiencies of nitrogen source removal with an alternative carbon source for the cost reduction. The 6.5mg 1(-1) and 5.7mg l(-1) of total nitrogen (TN) concentration in the effluent were achieved with mecellulose and methanol, whereas mecellulose and methanol were fed to give the same ratio of gCODgNO,-N(-1), respectively. The 60% of COD in mecellulose wasted liquor was used as a carbon source for denitrification and the stable denitrification rate was earned when one half of the required total carbon source for denitrification was fed to pre-anoxic tank in the pilot plant. The required gCODgNO,-N(-1) ratio with mecellulose wasted liquor was 1.4 times higher than with methanol. Mecellulose wasted liquor is feasible to be used as external carbon source for organic loading, nitrogen and phosphorus removal. If mecellulose wasted liquor is considered as an alternative external carbon source to substitute methanol 26-28m3 mecellulose wasted liquor per 1 m3 methanol will be required. However, to meet with the effluent standard (10 mg BOD l(-1)) for J-Municipal Sewage Treatment Plant, the feed concentration of mecellulose wasted liquor should be recommended to be lower than 200 mgl(-1).
研究了利用微晶纤维素废液(MWL)作为外部碳源,以寻找两级反硝化中试过程中甲醇的替代物。中试装置采用韩国J市污水处理厂(J-MSTP)的原水。由于工业废水和垃圾渗滤液的流入,J市污水处理厂的原水分别含有低浓度和高浓度的可生物降解有机物及氮源。在该J市污水处理厂中,投加甲醇以提供外部碳源,通过反硝化去除高浓度的氮源,因此本研究旨在测试使用替代碳源对出水水质和氮源去除效率的影响,以降低成本。使用微晶纤维素和甲醇时,出水总氮(TN)浓度分别达到6.5mg l(-1)和5.7mg l(-1),而投加微晶纤维素和甲醇时gCODgNO,-N(-1)的比例相同。微晶纤维素废液中60%的化学需氧量(COD)用作反硝化的碳源,当中试装置中反硝化所需总碳源的一半投加到预缺氧池中时,可获得稳定的反硝化速率。使用微晶纤维素废液时所需的gCODgNO,-N(-1)比例比使用甲醇时高1.4倍。微晶纤维素废液用作有机负荷、脱氮除磷的外部碳源是可行的。如果将微晶纤维素废液视为替代甲醇的外部碳源,则每1立方米甲醇需要26 - 28立方米微晶纤维素废液。然而,为了满足J市污水处理厂的出水标准(10mg BOD l(-1)),建议微晶纤维素废液的进料浓度低于200mgl(-1)。